Based on the provincial panel data of China in the last ten years, this paper uses panel entropy method and dual fixed model to explore the impact of digital economy on employment and industrial structure, and does heterogeneity research according to the economic development of low, medium and high economic development regions. The results show that the digital economy has a good promoting effect on the primary and tertiary industries, but has an inhibiting effect on the secondary industries. According to the results, the paper puts forward some policy suggestions on the use of digital economy development, industrial upgrading and employment promotion. In order to provide an important theoretical basis for the formulation and improvement of employment policies in the world economic system and the development of digital economy.